Evolution of surface morphologies in multivariant assemblies of surface-tethered diblock copolymers after selective solvent treatment.

نویسندگان

  • Michael R Tomlinson
  • Jan Genzer
چکیده

We study systematically the topography behavior of PHEMA-b-PMMA block as a function of the PHEMA and PMMA block lengths after selectively collapsing the top (PMMA) block by using surface-anchored assemblies of poly(2-hydroxyethyl methacrylate-b-methyl methacrylate), PHEMA-b-PMMA, block copolymer with orthogonally varying lengths of each block. Our experimental results are in excellent qualitative agreement with topology diagrams predicted by self-consistent field calculations of Zhulina and co-workers.

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عنوان ژورنال:
  • Langmuir : the ACS journal of surfaces and colloids

دوره 21 25  شماره 

صفحات  -

تاریخ انتشار 2005